July 28, 2008


Hard Water, Soft Solutions

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By Stuart A. Hoenig

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The USDA has determined that some 65% of the water in the USA is “hard” with a pH>7.2. The problem seems to be worst in the West where the Colorado River (the lifeblood of Arizona, Nevada and parts of California) is pH=8.3 to 8.5.

If hard water is used for farming or ornamental vegetation, the salts in the water are left in the soil. The Agricultural Salinity Assessment and Management, Manual 71, 1991, of the American Society of Civil Engineers, defines the Sodium Adsorption Ratio as a maximum of 15%. Above that level nothing will grow; growers should be aware that parts of Arizona have reached that limit and have been abandoned.

Another problem with hard water is that underground irrigation cannot be used because the small tubes are easily plugged by salt compounds. Some attempt has been made to use hard water underground and then to flush the tubes with dilute sulfuric acid. This may clean the tubes, but the hard water with its load of salts is still left in the soil.

The last question that might be asked is “What pH do plants prefer? Plants generally prefer neutral or slightly acidic water.

Solutions to the Problem

Reverse Osmosis

At present the most common technique is reverse osmosis.  This system is expensive to build and maintain. The purified water is satisfactory for household use, but is too expensive for agriculture.

Reducing the pH With Dilute Acids

1)  The use of CO2 or other dilute acid has a number of advantages. The CO2 dissolves rapidly in the hard water. The salts in solution become solidified and can be removed by a filtering system.

2)  The water is now softened and underground irrigation     can be used. Experience in Arizona is that underground irrigation requires approximately 50% of the water used for spray or ditch irrigation.

3)  The use of soft water gradually changes the ground from the normal alkaline condition (in the West) to a more acid state which helps the plants grow

4)  One last factor is that the use of CO2 is a natural part of the anaerobic digestion process used for disposal of garbage and waste water. The City of San Francisco disposes of its garbage using anaerobic digestion.  As a result, it generates CO2 and methane (which is sold to some 30,000 homes for heating) and the solids are sold to the public for fertilizer.

5)  The cost, assuming that CO2 is purchased commercially, is 49 cents per thousand gallons of water

Conclusions

The use of CO2 for water softening is low cost, rapid, simple, and good for plants; the resulting solid salts are easily disposed of by burial. The CO2 is permanently removed from the atmosphere. 

 

 

 

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